Ring-Opening Metathesis Copolymerization of Macrocyclic Olefin and Synthesis of Cyclic Polymers 大环烯烃参与的开环易位共聚合及环状聚合物的合成与表征
Ring-opening copolymerization of phthalic anhydride ( PA) with propylene oxide ( PO) was successfully carried out by using double-metal cyanide ( DMC). The characteristics of the copolymerization were presented and discussed. The structure of the copolymer was characterized with IR and 1H-NMR. 采用双金属氰化络合物(DMC)催化环氧丙烷(PO)和邻苯二甲酸酐(PA)共聚,探讨了共聚合特征,并用IR、1HNMR和GPC对共聚物的结构和分子量进行了表征。
Poly ( DL-lactide-co-glycolide)( PDL-LGA) copolymers with different DL-lactide/ glycolide ( DL-LA/ GA) mole ratios were prepared by bulk ring-opening copolymerization of DL-LA with GA using tin octoate ( Sn ( Oct) 2) as catalyst. 以辛酸亚锡为催化剂,通过本体开环聚合合成了不同摩尔比的DL丙交酯乙交酯(DLLAGA)共聚物(PDLLGA)。
Bulk ring-opening copolymerization of γ-valerolactone(γ-VL) and ε-caprolactone(ε-CL) was carried out with boron trifluoride etherate complex ( BF_3 · OEt_2) as catalyst. 以三氟化硼乙醚络合物为催化剂,进行了γ-戊内酯(γ-VL)与ε-己内酯(ε-CL)的本体开环共聚的研究。
Ring-opening copolymerization of γ-valerolactone and ε-caprolactone catalyzed by boron trifluoride etherate 三氟化硼-乙醚络合物催化γ-戊内酯与ε-己内酯开环共聚的研究
Ring-opening copolymerization of maleic anhydride and propylene oxide by fe-al-α,α′-dipyridyl catalyst Fe-Al-α,α′-联吡啶催化体系催化马来酸酐与环氧丙烷开环共聚
Methods The PLGA-ASP-PEG tri-block copolymers were obtained through bulk ring-opening copolymerization method. 方法本体开环共聚法合成PLGA-ASP-PEG三嵌段共聚物。
PLGA-[ ASP-PEG] was obtained by bulk ring-opening copolymerization method, examined by infrared spectrometry ( IR) and 1H nuclear magnetic resonance spectroscopy ( 1H NMR). 通过本体开环共聚方法合成PLGA-[ASP-PEG]多元共聚物,进行红外光谱(IR)和核磁共振氢谱(1HNMR)分析;